View Sidebar

学术业绩(Academic Achievements)

1. 电解质溶液组分活度研究

1. H. Yang, D. Zeng, W. Voigt, G. Hefter, Sh. Liu, Q. Chen, Isopiestic Measurements on Aqueous Solutions of Heavy Metal Sulfates: MSO4+H2O(M=Mn,Co,Ni,Cu,Zn) at T=323.15 K. J. Chem. Eng. Data, 59(2014) 97-102.


我们率先测定了重金属(Mn, Co, Ni, u, Zn)硫酸盐水溶液在高于25度时的水的活度,与在25度一样,在同等浓度下,硫酸锰水溶液的水的活度普遍高于其它重金属硫酸盐





2) 我们测定了三元体系LiNO3+KNO3+H2O在0度和25度下水的活度,数据用于模型参数优化,以便用于该体系相图预测。(D. Zeng*, Z. Wu, Y. Yao, H. Han, Isopiestic Determination of water activity on the system LiNO3+KNO3+H2O at 273.1 and 298.1 K, J Solution Chem., 39 (2010) 1360-1376.)


 


 

2) L. Guo, B. Sun, D. Zeng*, Y. Yao, H. Han, Isopiestic Measurement and Solubility Evaluation of the Ternary System LiCl−SrCl2−H2O at 298.15 K, J. Chem. Eng. Data, 57 (2012) 817-827.(Sci)

3) L. Guo, D. Zeng*, Y. Yao, H. Han, Isopiestic measurement and solubility evaluation of the ternary system (CaCl2+SrCl2+H2O) at T=298.15 K, J. Chem. Thermodynamics, 63 (2013) 60-66.(Sci)

4) 

5)

2. 电解质溶液结构研究

1) W. Voigt, K. Dittrich, D. Zeng, Ion coordination and thermodynamic modelling of molten salt hydrate mixtures, in the book: “Thermodynamic Properties of Complex Fluid Mixtures”, Wiley-VCH Verlag GmbH & Co. KGaA, ISBN 3-527-27770-6, 2004, p241-267.

2) F. Xia, H. Yi, D. Zeng*, Hydrates of Copper Dichloride in Aqueous Solution: A Density Functional Theory and Polarized Continuum Model Investigation, Polarized Continuum Model Investigation, J. Phys. Chem. A 113 (2009) 14029-14038. (Sci)

3) F. Xia, H. Yi*, D. Zeng*, Hydrates of Cu2+ and CuCl+ in dilute aqueous solution: a density functional theory and polarized continuum model investigation, J. Phys. Chem. A 114 (2010) 8406-8416. (Sci)

4) H. Yi*, F. Xia, Q. Zhou, D. Zeng*, [CuCl3] and [CuCl4]2- Hydration in Concentrated Aqueous Solution: a density functional theory and ab inition study, J. Phys. Chem., 115 (2011) 4416-4426.(Sci)

5) F.F. Xia, D. Zeng*, H.B. Yi, Ch.H. Fang, Direct Contact versus Solvent-shared Ion Pairs in Saturated NiCl2 Aqueous Solution: A DFT, CPMD, and EXAFS Investigation, J. Phys. Chem. A., 117 (2013) 8468-8476.

6) N. Zhang, Q. Zhou, X. Yin, D. Zeng, Trace amounts of aqueous opper(II) chloride complexes in hypersaline solutions: spectrophotometric and thermodynamic studies. J. Solution Chem. 43 (2014) 326-339.

7) N. Zhang, D. Zeng,* G. Hefter, Q. Chen, Chemical speciation in concentrated aqueous solutions of CuCl2 using thin-film UV–visible spectroscopy combined with DFT calculations, J. Molecular Liquids, 198 (2014) 200-203.

8)

3. 电解质溶液热力学模型研究

1) 尹霞,万艳鹏,李碧海,曾德文*, 高溶解性盐水体系热力学模型预测能力的比较研究I: 二元体系,化学学报,66 (2008) 1815-1826. (Sci)

2) Q. Zhou, D. Zeng*, W. Voigt, Thermodynamic modeling of salt-water systems up to saturation concentrations based on solute speciation: CuCl2–MCln–H2O at 298 K (M = Li, Mg, Ca), Fluid Phase Equilibria, 322-323 (2012) 30-40.(Sci)

4. 盐水化合物相变储能材料研究

1) W.Voigt,; D. Zeng, Solid-liquid equilibria in mixtures of molten salt hydrates for the design of heat storage materials, Pure and Applied Chemistry, 74 (2002) 1909-1920. (Sci)

2) W. Voigt, K. Rudolf, D. Zeng, High-Throughput-Techniken in der Kristallisationsforschung, Moderne Methoden zur Untersuchung von Löse- und  Kristallisations prozessen, Freiberg Forschungshefte, (2002) 169-182.

3) D. Zeng, W. Voigt, Phase diagram calculation of molten hydrates using the modified BET equation, C ALPHAD, 27 (2003) 243-251. (Sci, Ei)

4) D. Zeng, C. Fang, S. Chen, Phase diagram prediction of the heat storage systems Mn(NO3)2– M(NO3)n-H2O (M=Ca, Mg and Li) with modified BET-Model, Trans. Nonferrous Met. Soc. China, 14 (2004) 1192-1198. (Sci, Ei)

5) 尹霞,吴玉双,李琴香,曾德文*, 王成.  LiNO3-KNO3-H2O三元体系相平衡研究. 无机化学学报,26(1) (2010) 45-48. (Sci)

6) B. Li, D. Zeng*, X. Yin, Q. Chen, Theoretical prediction and experimental determination of room-temperature phase change materials using hydrated salts as agents. J. Therm. Anal. Calorim. 100 (2010) 685-693. (Sci)

7) X. Yin, Q. Chen, D. Zeng*, W. Wang, Phase Diagram of the System KNO3 + LiNO3 + Mg(NO3)2 + H2O, CALPHAD, 35 (2011) 463-472.(Sci)

8) O. Dong, D. Zeng*, H. Zhou, H. Han, X. Yin, Y. DU. Phase change materials in the ternary system NH4Cl-CaCl2+H2O, CALPHAD, 35 (2011) 269-275.(Sci)

9) 尹霞,陈启元,王文磊,曾德文*,四元体系LiNO3-Mg(NO3)2-NH4NO3-H2O相图预测及相关相变储能材料的研究,无机化学学报,28(2012) 1873-1877. (Sci)

10) 尹霞,陈启元,曾德文*,杜勇,用于室温相变储能材料的NaNO3-LiNO3-KNO3-H2O体系相图预测,中国有色金属学报,22 (2012)2875-2881. (Ei)

11) X. Yin, X. Yu, X. Wu, X. Fu, H. Wu, D. Zeng, Solubility Prediction and Measurement of the System KNO3−LiNO3−NaNO3−H2O, J. Chem. Eng. Data, 58 (2013) 1839-1844. (Sci)

5. 湿法冶金过程相平衡

1) 王文磊,曾德文*,杜勇,陈启元.重金属湿法冶金过程中钙镁结晶的工业现状及相关相图研究进展.中国科学:化学,40(9) (2010) 1226-1242.

2) D. Zeng*, W. Wang, Solubility phenomena involving CaSO4 in hydrometallurgical process concerning heavy metals, Pure and Applied Chemistry, 83 (2011) 1045-1061.(Sci)

3) W. Wang, D. Zeng*, X. Yin, Q. Chen, Prediction and Measurement of Gypsum Solubility in the Systems CaSO4+HMSO4+H2SO4+H2O(HM=Cu,Zn,Ni,Mn) at 298.15 K, Ind. Eng. Chem. Res., 51 (2012) 5124-5134. (Sci)

4) W. Wang, D. Zeng*, Q. Chen, X. Yin, Experimental determination and modeling of gypsum and insoluble anhydrite solubility in the system CaSO4-H2SO4-H2O, Chem. Eng. Sci., 101 (2013) 120-129. (Sci)

5)

6. 盐湖化工过程相平衡

1) D. Zeng, H. Liu, Q. Chen, Simulation and prediction of solubility phase diagram for the separation of MgCl2 from LiCl brine using HCl as a salting-out agent, Hydrometallurgy, 89 (2007) 21-31. (Sci, Ei)

2) 明键伟, 徐文芳, 曾德文*, 三元体系LiCl-LiNO3-H2O 273.15 K和323.15 K等温溶解度的测定, 无机化学学报, 22(5) (2007) 883-886. (Sci)

3) D. Zeng, J. Ming, W. Voigt, Thermodynamic study of the system LiCl-LiNO3-H2O, J. Chem. Thermodynamics, 40 (2008) 232-239. (Sci)

4) D. Zeng, W. Xue, W. Voigt, X. Yin, Thermodynamic study of the system LiCl-CaCl2-H2O, J. Chem. Thermodynamics, 40 (2008) 1157-1165. (Sci)

5) H. Ouyang, D. Zeng*, H. Zhou, H. Han, Y. Yao, Solubility of the ternary system LiCl+NH4Cl+H2O, J. Chem. Eng. Data., 56 (2011) 1096-1104.(Sci)

6) D. Zeng*, Solubility Phenomena, Chemistry International, 35(No.3) (2013) 32-34. 7) H. Yang, D. Zeng*, T. Liang, X. Yin, Q. Chen, Experimental determination and modeling of the solubility phase daigram of the quaternary system MgCl2+LiCl+NH4Cl+H2O at 298.15 K and its applications in industry, Ing.Eng.Chem.Res., 52 (2013) 17057-17063.

8) P. Song. B. Sun, D. Zeng, Solubility Phenomena Studies Concerning Brines in China, Pure and Applied Chemistry, 85 (3013) 2097-2116.

9) H. Zhou, D. Zeng*, H. Han, O. Dong, D. Li, Y. Yao, Solubility Isotherm of the System Li2SO4−K2SO4−MgSO4−H2O at 273.15 K, J. Chem. Eng. Data, 58 (2013) 1692-1696.(Sci)

7. 盐水体系相平衡实验数据评估

1) D. Zeng, J. Zhou, Thermodynamic consistency of the solubility and vapor pressure of a binary saturated salt + water system. I. LiCl + H2O, J. Chem. Eng. Data, 51 (2006) 315-321.(Sci, Ei)

2) D. Zeng, H. Zhou, W. Voigt, Thermodynamic consistency of the solubility and vapor pressure of a binary saturated salt + water system. II. CaCl2 + H2O, Fluid Phase Equilibria, 253 (2007) 1-11. (Sci)

3) T. Mioduski, C. Gumiski, D. Zeng*, IUPAC-NIST Solubility Data Series. 14. Rare Earth Metal Chlorides in Water and Aqueous Systems. Part 1. Scandium Group (Sc, Y, La), J. Phys. Chem. Ref. Data, 37 (2008) 1765-1853. (Sci)

4) T. Mioduski, C. Gumiski, D. Zeng*, IUPAC-NIST Solubility Data Series. 87. Rare Earth Metal Chlorides in Water and Aqueous Systems. Part 3. heavy Lanthanides (Gd-Lu), J. Phys. Chem. Ref. Data, 38 (2009) 925-1011. (Sci)

5) T. Mioduski, C. Gumiski, D. Zeng*, IUPAC-NIST Solubility Data Series. 87. Rare Earth Metal Chlorides in Water and Aqueous Systems. Part 2. Light Lanthanides (Ce-Eu), J. Phys. Chem. Ref. Data, 38 (2009) 441-562. (Sci)

6) H. Gamsjaeger, M. C. F. Magalhães, E. Königsberger, K. Sawada, B. R. Churagulov, P. Schmidt, D. Zeng, IUPAC-NIST Solubility Data Series. 92. Metal Carbonates. Part 1. Solubility and Related Thermodynamic Quantities of Cadmium(II) Carbonate in Aqueous Systems, J. Phys. Chem. Ref. Data, 40 (2011) 043104-1-043104-26.

7) C. Gumiński, H. Voigt, D. Zeng, Solubility of Rare Earth Metal Bromides and Iodides in Aqueous Systems, Monatsh. Chem., 142 (2011) 211-218. (Sci)

8) T. Mioduski, C. Gumiński, and D. Zeng*, IUPAC-NIST Solubility Data Series. 94. Rare Earth Metal Iodides and Bromides in Water and Aqueous Systems. Part 1. Iodides, Phys. Chem. Ref. Data 41, (2012) 013104-1-013104-63. (Sci)

9) H. Yang, D. Zeng*, Comment on “Thermodynamic properties of the ternary system {yNH4Cl-(1-y)MgCl2}(aq) at 298.15K” by Guedouzi et al. [Fluid Equilib. 53 (2007) 81-87], Fluid Phase Equilibria, 358 (2013) 326-328.

8. 专著 (books) 

1. D. Zeng, Thermodynamische Modellierung von Salz-Wasser-Systemen von der Lösung bis zur Salzschmelze, Shaker Verlag, ISBN: 3-8322-1844-0, (in German), 2003。       LiNO3+KNO3+H2O at 273.1 and 298.1 KLiNO3+KNO3+H2O at 273.1 and 298.1 KLiNO3+KNO3+H2O at 273.1 and 298.1 K,。(H. Yang, D. Zeng, W. Voigt, G. Hefter, Sh. Liu, Q. Chen, Isopiestic Measurements on Aqueous Solutions of Heavy Metal Sulfates: MSO4+H2O(M=Mn,Co,Ni,Cu,Zn). 1. T=323.15 K. J. Chem. Eng. Data, 59(2014) 97-102.)